\(a)Zn + 2H_2SO_4 \to ZnSO_4 + SO_2 + 2H_2O\\ n_{Zn} = n_{SO_2} = \dfrac{1,568}{22,4} = 0,07(mol)\\ \Rightarrow m_{ZnO} = 16,7 -0,07.65 = 12,15(gam)\\ \%m_{ZnO} = \dfrac{12,15}{16,7}.100\%= 72,75\%\\ b) n_{ZnSO_4} = n_{Zn} + n_{ZnO} = 0,07 + \dfrac{12,15}{81} = 0,22(mol)\\ m_{ZnSO_4} = 0,22.161 = 35,42(gam)\)

\(n_{SO_2}=\dfrac{1.568}{22.4}=0.07\left(mol\right)\)

\(Zn+2H_2SO_{4\left(đ\right)}\underrightarrow{^{t^0}}ZnSO_4+SO_2+2H_2O\)

\(0.07......................................0.07\)

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

\(m_{ZnO}=0.07\cdot65=4.55\left(g\right)\)

\(m_{ZnO}=16.7-4.55=12.15\left(g\right)\)

\(\%ZnO=\dfrac{12.15}{16.7}\cdot100\%=72.75\%\)

\(n_{ZnO}=\dfrac{12.15}{81}=0.15\left(mol\right)\)

\(m_{ZnSO_4}=\left(0.07+0.15\right)\cdot161=35.42\left(g\right)\)

Chọn A

Ta có:  m h h   =   9 , 2   g → 27a + 65b = 9,2 (*)

Bảo toàn số mol electron có: 3a + 2b = 0,5 (**)

Giải (*), (**): a = b = 0,1 mol.

m A l   =   0 , 1 . 27   =   2 , 7   g a m

Đáp án A.

Đáp án A.

Gọi n_Al = a mol, n_Zn = b mol.

Ta có: 27a + 65b = 9,2 (*)

         3a + 2b = 0,5 (**)

Giải (*), (**): a = b = 0,1 mol.

m_Al = 0,1.27 = 2,7 gam

\(a) 2Fe + 6H_2SO_4 \to Fe_2(SO_4)_3 + 3SO_2 + 6H_2O\)(Phản ứng oxi hóa-khử)

\(Fe_2O_3 + 3H_2SO_4 \to Fe_2(SO_4)_3 + 3H_2O\)

\(b) n_{SO_2} = \dfrac{672}{1000.22,4} = 0,03(mol)\\ n_{Fe}= \dfrac{2}{3}n_{SO_2} = 0,02(mol)\\ \%m_{Fe} = \dfrac{0,02.56}{2,72}.100\% = 41,18\%\\ \%m_{Fe_2O_3} = 100\% -41,18\% = 58,82\%\)

Đáp án B

Đặt n_Cu = x(mol); n_Zn=y(mol)

=> 64x + 65y = 12,9

Bảo toàn electron ta lại có: n_{e nhường} = n_{e nhận}

_{=> 2 . n Cu + 2 . n Zn = 2 n SO 2 + 6 n S}

=> 2x + 2y = 0,4 => x = y = 0,1 (mol)

Vậy phần trăm khối lượng mỗi kim loại trong hỗn hợp ban đầu là:

\(n_{Fe}=a\left(mol\right),n_{Zn}=b\left(mol\right)\)

\(m=56a+65b=13.22\left(g\right)\left(1\right)\)

\(n_{H_2}=\dfrac{4.928}{22.4}=0.22\left(mol\right)\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

\(n_{H_2}=a+b=0.22\left(mol\right)\left(2\right)\)

\(\left(1\right),\left(2\right):\)

\(a=0.12\)

\(b=0.1\)

\(\text{Bảo toàn e : }\)

\(n_{Zn}+n_{Fe}=n_{SO_2}=\dfrac{0.12}{2}+\dfrac{0.1}{2}=0.11\left(mol\right)\)

\(V_{SO_2}=0.11\cdot22.4=2.464\left(l\right)\)

`2Fe + 6H_2 SO_[4(đ,n)] -> Fe_2(SO_4)_3 + 3SO_2 \uparrow + 6H_2 O`

`0,05`        `0,15`                               `0,025`                                     `(mol)`

`Cu + 2H_2 SO_[4(đ,n)] -> CuSO_4 + SO_2 \uparrow + 2H_2 O`

`0,225`     `0,45`                         `0,225`                                          `(mol)`

`n_[SO_2]=[6,72]/[22,4]=0,3(mol)`

Gọi `n_[Fe]=x` ; `n_[Cu]=y`

`=>` $\begin{cases} \dfrac{3}{2}x+y=0,3\\56x+64y=17,2 \end{cases}$

`<=>` $\begin{cases}x=0,05\\y=0,225 \end{cases}$

  `@m_[Fe_2(SO_4)_3]=0,025.400=10(g)`

  `@m_[CuSO_4]=0,225.160=36(g)`

  `@m_[dd H_2 SO_4]=[(0,15+0,45).98]/80 .100=73,5(g)`

Sửa đề: 80% ---> 98% (80% chưa đặc nên không giải phóng SO₂ được)

Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Cu}=b\left(mol\right)\end{matrix}\right.\)

\(\rightarrow56a+64b=17,2\left(1\right)\)

PTHH: 

\(2Fe+6H_2SO_{4\left(đặc,nóng\right)}\rightarrow Fe_2\left(SO_4\right)_3+3SO_2\uparrow+6H_2O\)

a------>3a------------------->0,5a--------------->1,5a

\(Cu+2H_2SO_{4\left(đặc,nóng\right)}\rightarrow CuSO_4+SO_2\uparrow+2H_2O\)

b----->2b------------------->b------------->b

\(\rightarrow1,5a+b=\dfrac{6,72}{22,4}=0,3\left(2\right)\)

Từ \(\left(1\right)\left(2\right)\rightarrow\left\{{}\begin{matrix}a=0,05\left(mol\right)\\b=0,225\left(mol\right)\end{matrix}\right.\)

\(\rightarrow\left\{{}\begin{matrix}m_{Fe_2\left(SO_4\right)_3}=0,5.0,05.400=10\left(g\right)\\m_{CuSO_4}=0,225.160=36\left(g\right)\\m_{ddH_2SO_4}=\dfrac{\left(0,05.3+0,225.2\right).98}{98\%}=60\left(g\right)\end{matrix}\right.\)